
Charles asks…
what is the catalyst used in order to slow the decomposition of hydrogen peroxide(H2O2)?

admin answers:
Lancenigo di Villorba (TV), Italy
YOUR ANSWER
Hydrogen peroxide-based house-hold stuffs need
POLY-PHOSPHORIC ACID.
Why this stuff? It interacts with iron ions to avoid their chemical activities. Go to the underwritten.
GENERALITIES
I remember you that catalysts enhanced reaction’s rate.
In order to slow decomposition’s rate you use not a catalysts but other substances to avoid chemical species involved in decomposition of hydrogen peroxide.
How it proceeds the decomposition of hydrogen peroxide?
Many chemical compounds permit this reaction, among these there are manganese dioxide, iron salts.
The latters are most diffused pollutants of aqueous solutions as hydrogen peroxide-based house-hold stuffs.
DECOMPOSITION MECHANISM
Hydrogen peroxide was discovered by a french chemist (J. Thènard) in XIX century. In the century-endings, a chemical engineer (H. J. H. Fenton) discovered a novel reaction of hydrogen peroxide (original formulation interested a mixture of peroxide with ferrous sulphate and tartaric acid).
In the first half of XX century, several german chemists (Haber, Willstatter and Weiss) contribute to study the “Fenton’s reaction”.
They reported that following results :
-) ferrous sulphate enhance hydrogen decomposition as it is highlighted by oxygen gas bubbles collected;
-) ferric soluble salts show a lower activity than ferrous ones.
Nowadays, it is assumed that ferrous salts interact with hydrogen peroxide so ferrous ions become ferric ones.
Fe++(aq) + H2O2(aq) —> FeOH++(aq) + OH(aq)
As an acid species, hydrogen peroxide acts producing oxydril radical (e.g. OH) which is a very reactive intermeditae of this mechanism.
It begins a couple of reaction connected one to the other as a “chain model”.
OH(aq) + H2O2(aq) —> HO2(aq) + H2O(l)
HO2(aq) + H2O2(aq) —> O2(g) + OH(aq) + H2O(l)
This “reaction’s chain” involving another very reactive intermediate as hydroperoxide radical (e.g. HO2) and it produces water and oxygen as decomposition’s products. Finally, superoxide anions interact with ferric ions toward oxygen evolution.
FeOH++(aq) + HO2(aq) —> O2(g) + Fe++(aq) + H2O(l)
I hope this helps you.

Robert asks…
catalytic decomposition of hydrogen peroxide H2O2(aq) -> H2O(l) + O2(g) What are the stoichiometric coefficie

admin answers:
I think this means you need to balance the equation.
2H2O2(aq) –> 2H2O(l) + O2(g)
The stoichiometric coefficients are the numbers in front of the formulas.
Powered by Yahoo! Answers





